Episódios
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We reach the Big 1-5-0, in which I discuss the venerable history of mRNA vaccines, from the 1960s to the present, from a chemical point of view. We hear of transferring mRNA into cells, then transferring anti-viral mRNA into cells. There are a variety of mRNA vaccines under study--not merely COVID, but flu, RSV, and even cancer treatments. Patreon supporters may download a supplemental sheet with diagrams of some of the biochemical systems I describe.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In this episode we touch on how chemistry has directly influenced religion. Our example is how knowledge of chemistry affected a rabbi's decision to allow a certain brand of carbonated beverage to claim that it is kosher, that is, fit to be ingested by Jews who follow traditional Jewish laws and customs regarding food.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
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What if we could make flexible electronics for clothing or medical sensors? We examine the history of this quest from the 1990s onward, focusing on liquid-metal electronics. We explore what that means, the pros and cons, and how it might work. Then we talk about creating electronic components using wood (really!), which began in the 2010s, ranging from wooden batteries to wooden transistors.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
The history of chemistry in water microdroplets is discussed. We start with the observation by R. Graham Cooks that certain chemical reactions went faster inside ultra-small droplets of liquid relative to beaker-sized amounts. We examine the years-long arguments between Dick Zare and Himanshu Mishra over peroxide formation in microdroplets. We talk a bit about some reasons why reactions may go differently in tiny drops versus bulk amounts, and counter-arguments.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In this episode we examine the history of non-lithium batteries. We talk of changing the anode material and cathode material, whether separately or together. This involves changing the graphite anode to silicon, changing to sulfur anodes, air-based cathodes, different solvent molecules to assist transport of lithium ions, and even calcium batteries. Finally we discuss the flow battery, invented way back in the 19th century, but being revived for batteries that can be stationary.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In which we learn about the beginnings of chemistry applied to art conservation, from the initial attempts by Edward Forbes, but especially when he hired Rutherford John Gettens. We discuss Harvard University's Pigment Collection, plus various analytical tools chemists use to examine art, both light-based and non-light-based. We talk of several institutions with strong chemical applications for art conservation. Finally we examine the problems of modern products--polymers--that need to be preserved, from toys to photographic film.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Dear Listener,
I have been posting episodes weekly for two and a half years. I need a short break. I promise I will be back very soon. I have many more episodes already written and recorded for you. Please stay tuned. Until then….brave the elements!Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Here we explore the history of unusual and uncommon isotopes of known elements on the periodic table. We discuss the (almost) true statement that all isotopes of an element react the same. Then we reach inside the atomic nucleus and hear of theories to describe nuclear structure and--hence--stability of various isotopes, beginning with Dmitri Ivanenko's work. We learn of the best model, shell structure, and its failings that appeared in the 1980s. Then we talk about half-lives, and how short can a half-life be and still be an atom? How short can a half-live be and still be at least a nucleus? We learn of proton-rich isotopes. Then we hear of the practical value of such research.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In which I give a brief history of queer chemists. We talk of the rise of queer scientific associations, and the slog to acceptance of the Gay and Transgender Chemists and their Allies in the American Chemical Society, some current queer chemists around the world, and something of the challenge of queer chemists in the Britain.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Science-fiction writers (and scientists) have been promoting molecular transistors since the 1950s, and we explore the history of why that hasn't happened yet. We start with the parallel sci-fi writer (and biochemist) Isaac Asimov's "molecular valves" and physicist Arthur von Hippel's "molecular engineering." We talk of military projects that failed, and theoretical ideas that take a lot of engineering to make them work.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In this episode, I have a conversation with Professor David Perlmutter in the Communications Department at Texas Tech University, on the public's impressions of chemistry, and what value chemistry brings to the wider world.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
We start with the first chemical conspiracy theory from 1996, "chemtrails." Then we move to another popular chemical hoax, "alkaline water" somehow being healthy for you. Related to that are the bizarre "hexagonal water" and water memory ideas. Other creative pseudochemical hoaxes are denial of global warming and the gasoline pill, creating fuel from non-fuel with merely a pill in your liquid. There is the fun cryogenically-cooled audio cable hoax (if you are into high-fidelity audio). There was the truly harmful radioactive bed scandal in Korea. Finally I offer some clues to detecting such hoaxes and scams.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
A new material, the MXene, discovered in 2010, is the topic of this episode. We hear of its creation and derivation at Drexel University in Philadelphia. Then we learn of ways to create single layers, variations in materials, and new methods of synthesis of MXenes. Finally, we discuss the practical uses of MXenes.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
We finally get to discuss what the term "aromatic compound" means in chemistry, from Michael Faraday's report in 1825 of a new organic compound (we call it benzene), to von Hofmann's first use in 1856 (without defining it) of the term "aromatic". We examine the ensuing controversies and definitions of "aromatic compound," how people modeled molecularly and diagrammatically what that meant, and current discussions over the word. My Patreon supporters may download a supplemental sheet with molecular structures of some aromatic compounds I mention in the episode.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Aerogels, those feather-weight materials, have a century-old history. We begin with Samuel Kistler, the inventor of the first aerogels, and move forward through time with loss of interest in them, then revival of interest in the 1970s. We learn about gradual improvements in their fabrication over time. Then we talk of their fascinating properties, and then their uses.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Artificial intelligence, or AI, can be applied to chemistry, too. Here we discuss a brief history of AI, especially for chemistry, beginning with Djerassi's DENDRAL program. We talk of the current problems in chemistry to which AI is being applied over the last couple of decades. We also examine what is not doable (yet) in chemistry with AI.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In which we consider what, really, is a chemical bond. Lewis and Langmuir promoted the idea that bonding was sharing of electron pairs. Then we hear about Slater, Hellman, and Ruedenberg's discussion of how covalent bonding works. Kossel and Lewis also introduced ionic bonding. Finally Drude and Lorentz offered metallic bonding. But there are more chemical bonds: the hydrogen bond, the halogen bond, the mechanical bond, the van der Waals force, multi-center bonds, and metallophilic bonds.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
In which we talk about the fastest spectroscopy yet, attosecond spectroscopy, which can resolve electrons moving around atoms. The topic begins with Christian Spielmann in 1997, working to get shorter and shorter laser pulses, and continues with Ferenc Krausz. We discuss what you might be able to inspect using these short light pulses, such as how the shape of atomic orbitals oscillates after ionization, how you can change the opacity of a substance for a brief moment, and fluctuations of water structure.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
Instead of molecules that absorb light based on their molecular orbitals, this episode talks of nanostructures and their materials that refract light based on interference of light waves. We start with Robert Hooke who described this process in his book Micrographia. We continue through Isaac Newton and Lord Rayleigh. We discuss Eli Yablonovitch's photonic crystals. We mention various kinds of natural structural colorants in the living and non-living worlds, from minerals to insects to bacteria to plants. Then we list several attempts to synthesize structural colorants, and why they might prove useful.
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Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook -
This episode concerns the phenomenon in organic chemistry of classifying a set of similar reactions by a single umbrella name. Most named reactions honor a person, but not always. We discuss the early history of named reactions from the 1870s onward. We then talk about the slant of named reactions towards white men, and away from other people, and even whether that can be a problem for minority and women chemists. Patreon supporters may download a supplemental sheet that sketches some of the reactions I mention in the episode.
Support the show
Support my podcast at https://www.patreon.com/thehistoryofchemistry Tell me how your life relates to chemistry! E-mail me at [email protected] Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook - Mostrar mais